By Gilbert F. Froment, Kenneth B. Bischoff, Juray De Wilde
This is often the 3rd version of the traditional textual content on chemical response engineering, starting with uncomplicated definitions and basic rules and carrying on with the entire technique to sensible purposes, emphasising real-world points of business perform. the 2 major sections disguise utilized or engineering kinetics, reactor research and layout. contains up to date insurance of laptop modeling equipment and plenty of new labored examples. many of the examples use actual kinetic information from procedures of commercial value.
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Extra resources for Chemical Reactor Analysis and Design , 3rd Edition
Concentration-time profiles. 2-1. If experimental data on CA, CQ and CS versus time are available, the assumed orders can be checked and the values of k1 and k2 can be obtained by fitting the experimental curves. 2-1 Consecutive first order reactions. Concentration versus time profiles for various ratios of k2/k1. 2-9) which is, unlike for parallel reactions, a function of the conversion of the reactant A. The higher this conversion, the lower the selectivity towards the intermediate Q will be.
If experimental data on CA, CQ and CS versus time are available, the assumed orders can be checked and the values of k1 and k2 can be obtained by fitting the experimental curves. 2-1 Consecutive first order reactions. Concentration versus time profiles for various ratios of k2/k1. 2-9) which is, unlike for parallel reactions, a function of the conversion of the reactant A. The higher this conversion, the lower the selectivity towards the intermediate Q will be. Again yields can be used, of course.
May be called the “global order”, or generally just “order” of the reaction. 1-2) are strictly valid only for elementary reactions or steps. Some reactions consist of a number of elementary steps between intermediates with a short lifetime, less readily observable than the reactants and products. 1-1) do not necessarily correspond to the stoichiometric coefficients of the overall reaction. This is why it is recommended to verify the orders experimentally. 2 Influence of Temperature The rate of a reaction depends on the temperature, through the variation of its rate coefficient.